Spontaneous mirror symmetry breaking in heterocatalytically coupled enantioselective replicators.
نویسندگان
چکیده
Chiral hypercycle replicators (first-order autocatalysis together with mutual cross-catalysis) formed from achiral or racemizing resources may lead to spontaneous mirror symmetry breaking (SMSB) without the need for additional heterochiral inhibition reactions, such as those of the Frank-like models, which are an obstacle for the emergence of evolutionary selection properties. The results indicate that the chemical models for the emergence of primordial autocatalytic self-reproducing systems, of and by themselves, can also explain naturally the emergence of biological homochirality.
منابع مشابه
Spontaneous mirror symmetry breaking in heterocatalytically coupled enantioselective replicators† †Electronic supplementary information (ESI) available: Methods and text on stability analysis. Five figures showing simulation examples. See DOI: 10.1039/c6sc02446g Click here for additional data file.
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ورودعنوان ژورنال:
- Chemical science
دوره 8 1 شماره
صفحات -
تاریخ انتشار 2017